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X-Band Epr Imaging of Polymers Irradiated With Uv Light

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The determination of nitroxide radical distributions within polypropylene plaquettes containing amine stabilisers as well as other additives, which had been irradiated under air on one surface for several months, have been determined by an X-band EPR-Imaging apparatus. It is shown that the EPR Imaging technique represents a powerful tool for investigating the way in which the concentration inside polymers of nitroxide radicals changes both in time and in the space, thus providing information not easily obtainable by means of other techniques.

Affiliations: 1: Dipartimento di Chimica Organica "A. Mangini", Università di Bologna, Via S. Donato 15, 1-40127 Bologna, Italy; 2: Ciba-Geigy S.p.A. Divisione Additivi, Via Pila 6/3°, 1-40044 Pontecchio Marconi (BO), Italy


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