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Charge-Transfer Absorption of Olefins With Nitrosonium. Structural Relevance To the Dimethylbutene Complex With Dinitrogen Tetraoxide

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The transient electron donor-acceptor (EDA) complexes of various olefins (dimethylbutene, etc.) with the nitrosonium acceptor (NO+) show diagnostic charge-transfer absorption bands in dichloromethane solutions at low temperatures. Since the same charge-transfer absorption bands are observed when olefins are exposed to dinitrogen tetraoxide, they are ascribed to analogous EDA complexes [olefin, NO+] NO3- that are derived from the ionic disproportionation of nitrogen dioxide.

Affiliations: 1: Department of Chemistry, University of Houston, Houston, Texas 77204-5641, USA


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