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Reduction of Pyracylene By Alkali Metals: Mechanism and Formation of Aggregates

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Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed.

Affiliations: 1: Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel; 2: Merkert Chemistry Center, Boston College, Chestnut Hill, MA, 02167-3860 USA; 3: Institut für Physikalische Chemie der Universitat Basel, Klingelbergstr. 80 CH-4056 Basel, Switzerland


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