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Esr Molecular Dynamics Study At the Oxidation Sites of Polypropylene With Nitroxyl Spin Labels and Spin Probes

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Novel methods suitable for the selective insertion of nitroxyl spin labels and spin probes at the oxidation sites of isotactic polypropylene have been developed based on reactions with the oxidation products, on spin trapping with nitroso and nitrone compounds and taking advantage of the spontaneous generation of nitroxyl radicals as intermediates in the stabilization mechanism by the HALS. The analysis of the esr spectra of the doxyl spin label and of the spin probes from the HALS, performed according to the stochastic Liouville theory, has allowed information to be obtained on the molecular mobility at the oxidation sites as a function of the temperature.

Affiliations: 1: Dipartimento di Chimica Generale-Università di Pavia, Via Taramelli 12- 27100 Pavia, Italy; 2: Dipartimento di Scienza dei Materiali e della Terra Università di Ancona, Italy


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