Cookies Policy

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Radical Reactions of C84

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

This Article is currently unavailable for purchase.
Add to Favorites
You must be logged in to use this functionality

Cover image Placeholder

Pulse radiolysis and steady-state radiolysis experiments describing the radical and electron transfer reactions of C84 are reported here for the first time. C84 reacts readily with radiolytically generated chloromethyl (*CCl3) and trichloromethylperoxyl (CCl3OO*) radicals in CCl4. The formation of the radical adduct has been confirmed from its characteristic absorption in the UV (320 nm) and visible (480 nm). Radical-induced oxidation in 1,2-dichloroethane (1,2-DCE) resulted in a short lived transient absorbing at 920 nm. Reduction of C84 in toluene/2-propanol/acetone could be conveniently followed by formation of an absorption band with an absorption maximum at 960 nm.

Affiliations: 1: Notre Dame Radiation Laboratory, University ofNotre Dame, Notre Dame, Indiana 46556, U.S.A


Full text loading...


Data & Media loading...

Article metrics loading...



Can't access your account?
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation