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Radiation Chemical Investigations On Aqueous Solutions of C60(Oh)18

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The ultraviolet-visible absorption spectrum of C60(OH)18 in water showed an absorption band with λmax = 215 nm and other characteristic absorption bands of C60 are not observed. The singlet-singlet and triplet-triplet absorption bands are not observed in the 400 - 900 nm region. It has low reactivity with e-aq and formed an absorption band with λmax = 580 nm. The hydroxyl radicals react with a bimolecular rate constant of 2.4 x 109 dm3 mol-1 s-1 and showed an absorption band at 540 nm.

Affiliations: 1: Chemistry Division, Bhabha Atomic Research Centre, Bombay, 400 085, India; 2: Centre for Condensed Matter Science, National Taiwan University, Taipei, Taiwan 10764; 3: Chemistry Division, Bhabha Atomic Research Centre, Bombay, 400 085, India, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore, India


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