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Formation and Stabilization of Pd(Iii) in Presence of the Porphyrinato-Type Ligand Bilirubin

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Formation of transient Pd(III) species was established in the course of PdCl42--bilirubin (BR) reaction in basic-water medium. Using the EPR method the formation of an octahedral low-spin PdL.2H2O complex was proved exhibiting an anisotropic 2-component EPR spectrum (gl = 2.007 and gu = 1.998) and effective magnetic moment μeff = 1.7 BM.

Affiliations: 1: Department of Chemistry, University of Sofia, 1126 Sofia, Bulgaria

10.1163/156856797X00259
/content/journals/10.1163/156856797x00259
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/content/journals/10.1163/156856797x00259
2017-10-21

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