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The Thermal Decomposition of Hydrocarbons. Part 2. Alkylaromatic Hydrocarbons: Alkylbenzenes

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The pyrolysis of the n-alkylbenzenes is reviewed with emphasis on the radical chain mechanism and on the reactions of the intermediate radicals. The effects of the experimental conditions and conversion on the types and distribution of the final products are also evaluated. The Arrhenius rate parameters are summarized for both the elementary steps and the overall decomposition reactions.

Affiliations: 1: Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada, T6G 2G2


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