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Pulse Radiolysis Study of 2-Mercaptobenzothiazole--a Corrosion Inhibitor

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Pulse radiolysis of 2-Mercaptobenzothiazole (2-MBT) has been undertaken in aqueous solution. The semi-oxidized species formed at pH 4.5 due to the reaction of OH•, Br2- and N3• and at pH 10.5 with OH• yielded a spectrum with λmax = 348 and 595 nm. These semi-oxidized species were able to oxidize phenothiazine drugs (E° ≅ 0.8 V). Reducing species such as e-aq, CO2- and H• atoms react with 2-MBT resulting in the formation of a transient having λmax = 350 nm and reducing in nature. Kinetic and spectroscopic data of interest are reported.

Affiliations: 1: Chemistry Group, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India


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