Cookies Policy
X

This site uses cookies. By continuing to browse the site you are agreeing to our use of cookies.

I accept this policy

Find out more here

Photocatalytic Degradation of 4-Chlorophenol: a Mechanistically-Based Model

No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.

Brill’s MyBook program is exclusively available on BrillOnline Books and Journals. Students and scholars affiliated with an institution that has purchased a Brill E-Book on the BrillOnline platform automatically have access to the MyBook option for the title(s) acquired by the Library. Brill MyBook is a print-on-demand paperback copy which is sold at a favorably uniform low price.

Access this article

+ Tax (if applicable)
Add to Favorites
You must be logged in to use this functionality

image of Research on Chemical Intermediates

The photocatalytic degradation of 4-CP was mathematically modelled using the mechanistic insights and data presented in an earlier study [1]. The solution and surface concentrations of reacting species were calculated by solving a system of differential equations that account for oxidation reactions of dissolved and adsorbed species, adsorption and desorption, reduction of oxygen, and hole-electron recombination. The differential equations were integrated over discrete time-periods and annular regions of the photoreactor. The resulting model predicts the trends observed in studies in other laboratories using different experimental apparati. Using the model it is possible to predict effects of reactor geometry, TiO2 loading, light intensity, and mixing on the course of TiO2 photocatalytic oxidation. The model verifies the importance of surface reactions, and reveals the need to better understand the fate and role of oxygen in TiO2 photocatalytic systems.

Affiliations: 1: University of Notre Dame, Notre Dame, IN 46556, U.S.A

10.1163/156856797X00574
/content/journals/10.1163/156856797x00574
dcterms_title,pub_keyword,dcterms_description,pub_author
6
3
Loading
Loading

Full text loading...

/content/journals/10.1163/156856797x00574
Loading

Data & Media loading...

http://brill.metastore.ingenta.com/content/journals/10.1163/156856797x00574
Loading

Article metrics loading...

/content/journals/10.1163/156856797x00574
1997-01-01
2016-12-11

Sign-in

Can't access your account?
  • Tools

  • Add to Favorites
  • Printable version
  • Email this page
  • Subscribe to ToC alert
  • Get permissions
  • Recommend to your library

    You must fill out fields marked with: *

    Librarian details
    Your details
    Why are you recommending this title?
    Select reason:
     
    Research on Chemical Intermediates — Recommend this title to your library
  • Export citations
  • Key

  • Full access
  • Open Access
  • Partial/No accessInformation