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C-Alkylation of Methoxyphenols With Alcohols Over an Iron Catalyst

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The vapour phase alkylation of methoxyphenols with alcohols in the presence of an iron catalyst that contains Cr, Si and K oxides was studied. The reactions were carried out in a continuous process at atmospheric pressure. It is possible to receive ortho alkylated derivatives of 3- and 4-methoxyphenol with high yield and selectivity.

Affiliations: 1: 'Department of Catalysis, W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wroclaw 2, P.O. Box 937, Poland; 2: Institute of Organic Chemistry, Biochemistry and Biotechnology, Technical University of Wroclaw, Poland


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