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Recent Advances in Immobilization of Heteropolyacids

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image of Research on Chemical Intermediates

Freely water-soluble heteropolyacid could be made insoluble either by supporting on active carbon or by forming acidic cesium salts. In addition, 12-tungstophosphoric acid and its acidic cesium salt could be effectively immobilized in silica matrices by means of a sol-gel technique which involves the hydrolysis of ethyl orthosilicate to give insoluble, readily recoverable, and highly active solid acid catalysts for the hydrolysis of ethyl acetate.

Affiliations: 1: Department of Molecular Design and Engineering, School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-01, Japan

10.1163/156856798X00500
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/content/journals/10.1163/156856798x00500
1998-01-01
2017-05-22

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