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Electron Transfer. 137. Formal Potentials Involving Indium(Ii)

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Aqueous solutions of indium(III) undergo le- reductions by Sm(II) (E0 -1.55 V) and by Yb(II) (-1.05 V), but not by U(III) (-0.52 V). The facile and irreversible reduction, by In+aq5 of Ru(NH3)63+ (E0 +0.067 V) at reagent concentrations near 10-3 M implies a potential more negative than - 0.23 V for In(II,I) and, in conjunction with the known value of -0.44 V for In(III,I), a complementary potential less negative than -0.65 V for In(III,II). These observations, taken together, support le- indium potentials EoII,I -0.2 V and E0III,II -0.6 V.

Affiliations: 1: Department of Chemistry, Kent State University, Kent, Ohio 442421, U.S.A.

10.1163/156856798X00546
/content/journals/10.1163/156856798x00546
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2017-11-23

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