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Catalytic Transfer Hydrogenation of Olefins

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Catalytic transfer hydrogenation with simultaneous isomerization of 1-olefins (C6- C8), 1,3-cyclohexadiene, 1,7-octadiene and cyclohexene using ammonium formate on 3% Pd/C at 20°C in methanol was studied. The effect of the experimental procedure upon the hydrogenation course was discussed. The effect of applied donor quantity upon the hydrogenation selectivity and individual substrate reactivity was monitored.

Affiliations: 1: Institute of Chemical Technology, Department of Organic Technology, Technická 5, 166 28 Prague 6, Email:


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