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A Study On One-Electron Oxidation of Phenothiazine Derivatives Bv Piperidine Oxoammonium Ion in Sds Micelle

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N-Substituted phenothiazines were oxidized by 2,2,6,6-tetramethy-4-acetyloxypiperidine oxoammonium hexachloroantimonate (TAPO) to the corresponding radical cations in sodium dodecyl sulfate (SDS) micellar solution. The radical cations of phenothiazine derivatives were generated and stabilized by the anionic micelle in aqueous solution. An electron transfer mechanism has been proposed.

Affiliations: 1: Department of Chemistry, University of Science atid Technology of China, Hefei, 230026, P. R. China; 2: National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China; 3: Department of Chemistry, University of Science atid Technology of China, Hefei, 230026, P. R. China, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

10.1163/156856798X00582
/content/journals/10.1163/156856798x00582
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/content/journals/10.1163/156856798x00582
2017-08-18

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