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Photocyclisation of Aroyl-1,4-Quinones as Precursors for Anthracyclones and Heteroanthracyclones

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While pursuing our studies on the synthesis of anthracyclinones and heteroanthracyclinones. We have studied the photocyclisation of benzoyl-1,4-benzoquinones leading to xanthones and phenyl gentisate esters. To the best of our knowledge this is the first observation of photo-xanthone synthesis. Some mechanistic aspects of the reaction have been presented.

Affiliations: 1: Department of Chemistry, University of Rajasthan, Jaipur-302004, India; 2: Chemistry Division, Bhabba Atomic Research Centre, Mumbai-400085, India


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