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Alkylation of para-Cresol With Lower Alcohols Over an Iron Catalyst

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image of Research on Chemical Intermediates

The results of gas-phase alkylation of para-cresol (4-methylphenol) in the presence of an iron catalyst using methanol, ethanol, n- and iso-propanol as alkylating agents are presented. In the case of methylation and ethylation the total ortho-selectivities were nearly 100% and the yields of products were very high. The studies were carried out in a continuous process at atmospheric pressure. The obtained alkyl derivatives of para-cresol are important for industry as antioxidants and intermediates.

Affiliations: 1: Department of Catalysis, W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wroclaw, P.O. Box 1410, Poland; 2: Present address: Indian Institute of Petroleum, P.O. P Mohkampur, Dehra Dun - 248005, India


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