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Electron Transfer Studies With Fullerenes Incorporated Into Artificial Lipid Bilayer Membranes

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A systematic variation of functionalizing addends, covalently linked to the fullerene core, has been probed in light of facilitating fullerene incorporation into artificial lipid bilayer membranes. Electron transfer studies, by means of time-resolved pulse radiolysis, show that structurally balanced fullerene derivatives were successfully incorporated into various vesicular matrices which, in turn, enabled a very efficient fullerene reduction by hydrated electrons and *CH2OH radicals.

Affiliations: 1: Radiation Laboratory, University of Notre Dame, Notre Dame, IN 46556, USA


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