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Photoisomerization of Diethyloxadicarbocyanine Iodide in Dna and Protein#

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Photoisomerization of 3,3'-diethyloxadicarbocyanine iodide (DODCI) is studied in aqueous solution in the presence of salmon sperm DNA and bovine serum albumin (BSA). It is observed that in aqueous solutions DNA and BSA offer extremely high friction to the isomerization of DODCI, like a highly viscous liquid. As a result, the isomerization of DODCI is completely suppressed inside DNA and BSA.

Affiliations: 1: Department of Physical Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta 700 032, INDIA


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