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The t-0.6 Kinetic Law for Geminate Ion Kinetics and Its Applications To Non-Polar Solvents

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The t-0.6 rate law by van den Ende et al. (Radiat. Phys. Chem. 22, 55 1984) is one of several methods to describe the kinetics of geminate ion recombination. Due to its simplicity it is a very powerful tool to study geminate ion mechanisms. Complications occur if geminate ions react or fragment. The corresponding theory is given to include one additional ionic reaction and two parallel or two consecutive ionic reactions. The theory is applied to pulse radiolysis results in methylcyclohexane to illustrate the power of the method.

Affiliations: 1: Laboratory for Physical Chemistry, Swiss Federal Institute of Technology, ETH Zürich, Switzerland


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